I'm all for supporting the Starkville Cafe, however, I'd have a hard time passing the Tin Lizzie in West Point simply because it's just to convenient. Starkville and the Starkville Cafe will just be packed for game day traffic. Tin Lizzie would be easy to get into and out of.
Now, if you really want to experience a good Mississippi breakfast, then you can try the new Pheba Diner on HWY 50 in Pheba, MS. You'll get a great breakfast at a good price and probably be joined with half the deer hunters in the area. To get there from Booneville, just take HWY 45 South to West Point. At West Point, take HWY 50 West about 14 miles. The Pheba Diner will be on your left just after a blinking yellow light.
After breakfast, leave the diner going back East on HWY 50. Take a right at that blinking yellow light onto HWY 389 which will take you 12 miles right into Starkville.